No, not the one. I just got that Friends set for the hair. I thought I could find a minifig head to go with it. I'm gonna try searching for firefly mocs and see what they did for Zoe. I remember a while back there weren't any decent options, but for some reason I thought things had improved. Right now I'm trying the head from the Arkham Asylum guard. Don't like it, but I think the only other options I have on hand would be the plain smiley head from the Bespin guard or Mace Windu's head from a while back. I really want a female head though, with lipstick and stuff.
I've seen people use the generic smiley face from the bespin guard, but it looks at bit out of place amongst other more detailed prints.
I guess one may be made if TLG expanded the X-Men range (and make Storm) but I can't think of any other themes/sets that are likely to produce one, but surely there must be some random female star wars characters that they could have produced by now!